Pirolisin

Pirolisin
Wasta
	Wasta IUPAC N6-{[(2R,3R)-3-methyl-3,4-dihydro-2H-pyrrol-2-yl]carbonyl}-L-lysine
	Wasta IUPAC sistematik (2S)-2-amino-6-{[(2R,3R)-3-methyl-3,4-dihydro-2H-pyrrole-2-carbonyl]-amino}-hexanoic acid
	Wasta lian L-Pyrrolysine
Pananda
Nomer CAS	448235-52-7 ;
Modél 3D (JSmol)	Gambar interaktif; Zwitterion: Gambar interaktif;
ChEBI	CHEBI:21860 ;
ChemSpider	4574156 ;
KEGG	C16138 ;
PubChem CID	5460671;
UNII	H3214Y96LP ;
CompTox Dashboard (EPA)	DTXSID70420110 ;
	InChI InChI=1S/C12H21N3O3/c1-8-5-7-14-10(8)11(16)15-6-3-2-4-9(13)12(17)18/h7-10H,2-6,13H2,1H3,(H,15,16)(H,17,18)/t8-,9+,10-/m1/s1 Key: ZFOMKMMPBOQKMC-KXUCPTDWSA-N ; InChI=1/C12H21N3O3/c1-8-5-7-14-10(8)11(16)15-6-3-2-4-9(13)12(17)18/h7-10H,2-6,13H2,1H3,(H,15,16)(H,17,18)/t8-,9+,10-/m1/s1 Key: ZFOMKMMPBOQKMC-KXUCPTDWBO;
	SMILES C[C@@H]1CC=N[C@H]1C(=O)NCCCC[C@@H](C(=O)O)N; Zwitterion: O=C(NCCCC[C@@H](C(=O)[O-])[NH3+])[C@@H]1/N=C\C[C@H]1C;
Sipat
Rumus kimia	C12H21N3O3
Massa molar	255.313 g/mol
	Iwal disebutkeun séjén, data nu dipidangkeun keur matéri dina kaayaan baku (dina 25 °C, 100 kPa).
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“Pyl” dialihkeun ka dieu. Pikeun kagunaan séjén, tempo Pyl (disambiguasi).

Artikel ieu lain ngeunaan Pirolisis.

Pirolisin (lambang Pyl atawa O;^[1] anu dikode ku stop kodon UAG) nyaéta asam α-amino anu dipaké dina biosintésis protéin dina sababaraha archaea jeung baktéri métanogenik;^[2]^[3] teu aya di manusa. Pirolisin ngandung hiji gugus α-amino (wangun kaprotonan –NH+3 dina kaayaan biologis), hiji gugus asam karboxilat (wangun deprotonasi –COO⁻ dina kaayaan biologis). Ranté gigir pirrolin-na sarupa jeung dina lisin, watekna basa jeung boga muatan positip dina pH nétral.

Rujukan édit

↑ "Nomenclature and Symbolism for Amino Acids and Peptides". IUPAC-IUB Joint Commission on Biochemical Nomenclature. 1983. Diarsipkan dari versi asli tanggal 9 October 2008. Diakses tanggal 5 March 2018. Archived 9 Oktober 2008 di Wayback Machine
↑ Richard Cammack, ed. (2009). "Newsletter 2009". Biochemical Nomenclature Committee of IUPAC and NC-IUBMB. Pyrrolysine. Diarsipkan dari versi asli tanggal 2017-09-12. Diakses tanggal 2012-04-16.
↑ Rother, Michael; Krzycki, Joseph A. (2010-01-01). "Selenocysteine, Pyrrolysine, and the Unique Energy Metabolism of Methanogenic Archaea". Archaea 2010: 1–14. doi:10.1155/2010/453642. ISSN 1472-3646. PMC 2933860. PMID 20847933. http://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=2933860.

Atkins, J. F.; Gesteland, R (2002). "The 22nd Amino Acid". Science 296 (5572): 1409–1410. doi:10.1126/science.1073339. PMID 12029118.
Krzycki, J. A. (2005). "The direct genetic encoding of pyrrolysine". Current Opinion in Microbiology 8 (6): 706–712. doi:10.1016/j.mib.2005.10.009. PMID 16256420.

Wasta


Wasta IUPAC N⁶-{[(2R,3R)-3-methyl-3,4-dihydro-2H-pyrrol-2-yl]carbonyl}-L-lysine
Wasta IUPAC sistematik (2S)-2-amino-6-{[(2R,3R)-3-methyl-3,4-dihydro-2H-pyrrole-2-carbonyl]-amino}-hexanoic acid
Wasta lian L-Pyrrolysine
Pananda
Nomer CAS	448235-52-7^Y
Modél 3D (JSmol)	Gambar interaktif Zwitterion: Gambar interaktif
ChEBI	CHEBI:21860^N
ChemSpider	4574156^Y
KEGG	C16138^Y
PubChem CID	5460671
UNII	H3214Y96LP^Y
CompTox Dashboard (EPA)	DTXSID70420110
InChI InChI=1S/C12H21N3O3/c1-8-5-7-14-10(8)11(16)15-6-3-2-4-9(13)12(17)18/h7-10H,2-6,13H2,1H3,(H,15,16)(H,17,18)/t8-,9+,10-/m1/s1^Y Key: ZFOMKMMPBOQKMC-KXUCPTDWSA-N^Y InChI=1/C12H21N3O3/c1-8-5-7-14-10(8)11(16)15-6-3-2-4-9(13)12(17)18/h7-10H,2-6,13H2,1H3,(H,15,16)(H,17,18)/t8-,9+,10-/m1/s1 Key: ZFOMKMMPBOQKMC-KXUCPTDWBO
SMILES C[C@@H]1CC=N[C@H]1C(=O)NCCCC[C@@H](C(=O)O)N Zwitterion: O=C(NCCCC[C@@H](C(=O)[O-])[NH3+])[C@@H]1/N=C\C[C@H]1C
Sipat
Rumus kimia	C₁₂H₂₁N₃O₃
Massa molar	255.313 g/mol
Iwal disebutkeun séjén, data nu dipidangkeun keur matéri dina kaayaan baku (dina 25 °C, 100 kPa).
N verifikasi (naon ieu ^YN ?)
Rujukan kotak info