Bénzéna
Bénzéna | |
---|---|
Umum | |
Ngaran sistimatik | Bénzéna |
Ngaran lian | Bénzol |
Rumus molekul | C6H6 |
SMILES | C1=CC=CC=C1 |
InChI | InChI=1/C6H6 /c1-2-4-6-5-3-1/h1-6H |
Massa molar | 78.11 g/mol |
Panémbong | Cair teu warnaan |
Nomer CAS | [71-43-2] |
Pasipatan | |
Dénsitas jeung pase | 0.8786 g/cm³, cair |
Kaluyuran dina cai | 1.79 g/l (25 °C) |
Titik lééh | 5.5 °C (278.6 K) |
Titik golak | 80.1 °C (353.2 K) |
Viskositas | 0.652 cP at 20 °C |
Struktur | |
Bentuk molekul | Planar |
Gugus simétri | D6h |
Momen dipol | 0 D |
Bahya | |
MSDS | External MSDS |
EU classification | Gampang kaduruk Karsinogén Mutagén Toksik |
NFPA 704 | |
Frase-R | R45, R46, R11, R36/38, R48/23/24/25, R65 |
Frase-S | S53, S45 |
Flash point | −11 °C |
Autoignition temperature | 561 °C |
Nomer RTECS | CY1400000 |
Sanyawa nu patali | |
hidrokarbon nu patali |
siklohéksana naptaléna |
Sanyawaan nu patali | toluéna borazina |
Iwal mun disebutkeun sacara husus, data anu dipidangkeun téh pikeun bahan dina kaayaan baku (25°C, 100 kPa) Infobox disclaimer and references |
Bénzéna atawa bénzén, ogé katelah C6H6, PhH jeung bénzol mangrupa sanyawa organik nu wujudna cair teu warnaan, gampang kaduruk, sarta seungit kaambeuna. Bénzéna téh karsinogén, sahingga geus teu dipaké salaku aditif pikeun béngsin. Bénzéna kaasup salah sahiji pangleyur industri penting sarta bahan baku pikeun produksi ubar, plastik, karét sintétik, jeung pewarna. Bénzéna téh aya dina minyak bumi, tapi pikeun kaperluan industri mah sok disintésis tina sanyawaan séjén nu aya dina minyak bumi.
Sajarah
éditBénzéna kapanggih taun 1825 ku élmuwan Inggris Michael Faraday, nu ngisolasi tina gas minyak sarta dingaranan bicarburet of hydrogen. Taun 1833, kimiawan Jérman Eilhard Mitscherlich mroduksi ieu sanyawa tina distilasi asam bénzoat jeung kapur. Ku Mitscherlich ieu sanyawaan dingaranan benzin. Taun 1845, kimiawan Inggris Charles Mansfield, nu digawé ka August Wilhelm von Hofmann, ngisolasi bénzéna tina coal tar. Opat taun salajengna, Mansfield mitambeyan produksi bénzéna skala industri, dumasar kana métode coal-tar.
Rujukan
édit- Benzene, Wikipédia édisi basa Inggris (23 Méi 2006).
- Archibald Scott Couper, On a New Chemical Theory, Philosophical Magazine 16, 104-116 (1858)
- Josef Loschmidt, Chemische Studien I, Carl Gerold's Sohn, Vienna (1861),
- Josef Loschmidt, Chemische Studien I, Aldrich Chemical Co, Milwaukee (1989), catalog no. Z-18576-0, and (1913) catalog no. Z-18577-9
- Kathleen Lonsdale, "The Structure of the Benzene Ring in Hexamethylbenzene," Proceedings of the Royal Society 123A: 494 (1929).
- Kathleen Lonsdale, "An X-Ray Analysis of the Structure of Hexachlorobenzene, Using the Fourier Method," Proceedings of the Royal Society 133A: 536 (1931).
Tumbu kaluar
édit- ATSDR - Case Studies in Environmental Medicine: Benzene Toxicity Archived 2006-04-24 di Wayback Machine
- Benzene Archived 2007-02-02 di Wayback Machine
- Benzene Material Safety Data Sheet
- International Chemical Safety Card 0015
- National Pollutant Inventory - Benzene
- NIOSH Pocket Guide to Chemical Hazards
- IARC Monograph: "Benzene" Archived 2005-10-12 di Wayback Machine
- European Chemicals Bureau
- CID 241 ti PubChem
- Computational Chemistry Wiki
- Couper and Carbon bonds
- Dept. of Health and Human Services: TR-289: Toxicology and Carcinogenesis Studies of Benzene
- Kekule, Couper and dreams of Benzene
- Loschmidt's Benzene structure Archived 2009-01-02 di Wayback Machine
- Kekulés Traum (impian Kekulé, dina basa Jérman)
- video podcast (Ceramah Sir john Cadogan taun 1991)
Gugus Fungsi - édit |
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Kelas kimia: Alkohol | Aldehida | Alkana | Alkéna | Alkuna | Amida | Amina | Sanyawa azo | Turunan bénzéna | Asam karboksilat | Sianat | Éster | Éter | Haloalkana | Imina | Isosianida | Isosianat | Keton | Nitril | Sanyawa nitro | Sanyawa nitroso | Peroksida | Asam pospat | Turunan piridin | Sulfona | Asam sulfonat | Sulfoksida | Tioéter | Tiol | Turunan toluéna |